Department of Chemistry
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Item Synthesis and Characterization of PANI@cellulose Nanocomposite based Electrochemical Sensor for Environmental Remediation(Library Information Services COMSATS University Islamabad Lahore Campus, 2021-02-26) Nageen Shoukat; SP20-R06-010; Dr. Lubna Sherin; LHR TP 7564In this work, porous CuO-NiO/CA/PANI@Ni-foam sensor electrode has been designed using electospinning of CA/PANI composite on Ni-foam and then drop casting of CuO-NiO nanoparticles for detection of bisphenol A (BPA). 3D nickel foam has been chosen as electrode substrate for the direct growth of CA/PANI since Ni-foam has the advantages of excellent electrical conductivity, low cost, commercial availability, and porous structure, which provides large surface area for synthesis of nanofibers. This direct grown structure of CuO-NiO/CA/PANI@Ni-foam provides exceptional properties, such as reduced resistance, good electron transport, better adhesion stability and the excellent electrical conductivity as compared with non-direct synthesized electrode. Furthermore, a synergetic effect between CuO-NiO/CA/PANI and Ni-foam substrate enables the electrode for excellent sensing behavior towards BPA. The resultant CuO-NiO/CA/PANI@Ni-foam was analyzed using Fourier transform infrared spectroscopy, X-ray diffraction, Raman spectroscopy and scanning electron microscopy. Different electrochemical methods such as cyclic voltammetry, electrochemical impedance and differential pulse voltammetry were used for evaluation of synthesized sensor’s performance against BPA. Under optimal conditions, a linear response was observed against BPA and very low limit of detection as well (LOD=0.6uM). The CuO-NiO/CA/PANI@Ni-foam electrode demonstrated high reproducibility, consistency, and stability when used to detect BPA in water. The synthesized sensor's results demonstrated that it was extremely selective for the detection of BPA, suggesting that it could be useful in environmental based surveillances.Item Study of Cellulose-Based Nanocomposite Sheets for Potential Application in Flexible Electronics(Library Information Services COMSATS University Islamabad Lahore Campus, 2021-02-26) MUHAMMAD HABIB UR REHMAN; SP20-R06-017; Dr. Lubna Sherin; LHR TP 7571Cellulose, an abundant, cheap and bio-compatible polymer have been widely used in writing and packaging for decades. In modern world it has found a vast range of high tech applications such as flexible electronics. It is anticipated that use of cellulose substrate in flexible electronics can reduced millions tons of electronic waste. In this work lemongrass leaves were used as cellulose source to prepare cellulose sheets. The characterization techniques such as FTIR and XRD were used to confirm that fabrication of cellulose substrate. The analysis on cellulose substrate was performed by using two conventionally used methods in electronics e.g., electro spraying of conductive ink and adhesive copper tape. Poly 3, 4-ethylenedioxythiophene: Poly styrene sulfonic acid (PSS: PEDOT) was used as conducting ink for electro-spraying. The substrate, electro-sprayed for 6 minutes and curred at 80 °C for 40 minutes, showed remarkable results. Comparison of substrate behavior was made between synthesized cellulose substrate and commercially used reference PET substrate by using adhesive copper tape. Current-voltage measurement were recorded for the conductance study. Results of cellulose substrates behavior similar to that of reference substrate show that it can be a potential candidate of eco-friendly substrate for electronics; addressing the need for biodegradable, cost-effective and environment friendly green electronics especially in the fabrication of recyclable microwave components and antennas.