M.Phil / MS Theses
Permanent URI for this collectionhttps://repository.cuilahore.edu.pk/handle/123456789/27
This collection archives the complete set of theses produced by students of the COMSATS University Islamabad, Lahore Campus.
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Item Source Apportionment of PM2.5 in Lahore: Chemical Mass Balance Modeling and Inter-Study variability Assessment(Library Information Services, COMSATS University Islamabad, Lahore Campus, 2025) Muhammad Nabeel Khan; CIIT/FA23-RNE-04/LHR; Dr. Wajih Ur Rehman; LHR TP 10010Elevated concentrations of fine particulate matter (PM₂.₅) pose a serious public health risk in Lahore due to their ability to penetrate deep into the respiratory system. This thesis applies the U.S. Environmental Protection Agency Chemical Mass Balance receptor model (CMB v8.2) to apportion PM₂.₅ sources using three independent, chemically speciated datasets from Lahore: a winter campaign (February 2019), a year-long monthly study (2019), and paired summer–winter measurements (2022). U.S. EPA source profiles for gasoline and diesel vehicles, biomass burning, coal combustion, road/soil dust, industrial emissions, and secondary Sulfate and Nitrate were employed. Model performance was evaluated using standard diagnostics (R², χ², percent mass explained, t-statistics, and residuals). The winter 2019 analysis showed good model performance (R² = 0.72, χ² = 3.8), with dominant contributions from petrol vehicles (101 µg·m⁻³) and biomass burning (81 µg·m⁻³), along with substantial secondary Nitrate and Sulfate. Monthly CMB runs for 2019 yielded R² values between 0.73 and 0.87, indicating stable performance across seasons. Diesel vehicle emissions peaked during late autumn and winter, while petrol vehicle contributions increased in warmer months. Coal and industrial combustion, together with secondary inorganic aerosols, contributed persistently throughout the year. Seasonal analysis of 2022 data showed PM₂.₅ increasing from approximately 130 µg·m⁻³ in summer to 303 µg·m⁻³ in winter, with acceptable mass closure and statistically significant source contributions. Across all datasets, combustion-related sources—vehicular emissions, biomass burning, and coal combustion—along with seasonally enhanced secondary inorganic aerosols were the dominant contributors to PM₂.₅ in Lahore, while dust sources were more influential during pre-monsoon periods. These results provide higher source resolution than previous PMF/PCA studies and support targeted mitigation strategies focused on vehicle emissions, combustion sources, and precursor gas controlItem Development of Experimental Testing Facility for Performance Evaluation Triboelectric Nanogenerator Device(Library Information Services, COMSATS University Islamabad, Lahore Campus, 2025) Muhammad Nafees ul Hussain; CIIT/SP24-RNE-005/LHR; Dr Maria Mustafa; LHR TP 10011The study of Triboelectric Nanogenerators (TENGs) a flexible system to harvest low-frequency mechanical energy has become more accelerated by the increasing global demand on sustainable energy. But variable performance reporting in the field is often occasioned by lack of standardized and uniform testing conditions. This gap is covered by creating an in-house testing laboratory that will be utilized to precisely describe and quantify the durability of TENG devices. The two main parts of the experimental setup are an Arduino-controlled solenoid system that can perform independent testing at constant contact forces (2 N) and various periods of time, and a Dynamic Load Applicator (DLA) that can perform uniform cyclic endurance testing between 50-550 rpm. High-performance TENGs were created by evaluating the facility utilizing a polyvinylidene fluoride (PVDF) matrix covered with sodium niobate (NaNbO3) and carbon black (CB).Hydrothermal methods were used to create NaNbO3, and solution-based processing was used to install the thin film. Numerical outputs of the experiements highlighted facility's capacity to capture high-resolution data. The results suggest that the solenoid system was able to separate voltage peaks of up to 23V for PVDF+CB-NaNbO₃ combinations, while the DLA achieved maximum open-circuit voltages of 50 V for PVDF+CB-NaNbO₃ compositions. Sensitivity was exhibited by microampere-level current responses, which were 5.84 µA for PVDF+CB-NaNbO₃ utilizing the DLA and 5.62 µA for PVDF+NaNbO₃ utilizing the push-pull system. This study delivers a reliable and scalable setup for systematic TENG performance analysis that is significant for the development of self-powered devices and sensing technologies.Item Surface Modification of Layered Double Hydroxides for Reinforcement in Nitrile Butadiene Rubber(Library Information Services, COMSATS University Islamabad, Lahore Campus, 2025) Ahmad Ali; CIIT/SP22-RCH-002/LHR; Dr. Khaliq Majeed; LHR TP 10007This study examines the reinforcement of the nitrile butadiene rubber (NBR) composites with Zinc-aluminium layered double hydroxides (LDH) with sodium dodecyl sulfate (SDS) to enhance filler-matrix compatibility and mechanical properties. The pure LDH was prepared by the co-precipitation method, after which modification was done on the surface by the SDS, to enhance the hydrophobicity and interfacial contact with NBR. The successful intercalation of the SDS and increased basal spacing in the modified LDH were verified by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). Tensile tests on the modified and unmodified LDH-NBR composites showed that SDS modification had a significant enhanced dispersion behavior of the filler, which resulted in an enhancement of mechanisms. The force- elongation curves exhibited linear behavior to some elongation after which there was sudden material failure, which was regarded as tensile limits of the composite. Even though, the SDS-modified LDH-NBR composites exhibited better reinforcement than the unmodified systems, unexpected failure in higher elongations indicated that additional optimization is necessary in filler dispersion and bonding between phases. The study has given a valuable insight into the potential of SDS-modified LDH as a reinforcing agent in NBR composites, with future studies aiming to optimize the filler dispersion, investigate alternative methods of modification, and evaluate the long-term performance within different environmental conditions.Item Performance Analysis of Heat-Integrated LNG Regasification with Air Separation Units(Library Information Services, COMSATS University Islamabad, Lahore Campus, 2025) Muhammad Naeem Khalid; CIIT/FA23-RCH-005/LHR; Dr. Muhammad Haris Hamayun; LHR TP 10009Pakistan has a strong dependency on natural gas as an energy source to fulfil both the domestic and industrial requirements. Due to depletion of reserves of natural gas in Pakistan, this gas, in the form of liquefied natural gas (LNG), is imported, mainly from Qatar. However, there are several issues associated with this imported LNG. The LNG needs to be regasified before use in the existing infrastructure, the calorific value of imported LNG is higher than the design specifications, and the cold energy/exergy stored in LNG is wasted via the current method of regasification, mixing with the remaining reserves of natural gas. To overcome these issues, there is a need to integrate LNG regasification process with a process that can provide an inert, i.e., nitrogen to lower the calorific value of this LNG to meet the existing design specifications, to extract/use the cryogenic energy of LNG to lower the overall energy requirements, and eventually to regasified LNG for onward use by the users. Cryogenic air separation process appears to be the most suitable process for the integration with LNG regasification that can help in achieving the required objectives. Accordingly, this study aims to integrate the cryogenic air separation process and LNG regasification process, and the model is developed using Aspen HYSYS® V15. To the best of our knowledge, the developed process is examined using exergy, advanced exergy and exergoeconomic analyses, however, so far, optimization via evolutionary algorithm is not reported in literature. Therefore, this research gap is addressed in this study by employing teaching learning self-study-optimization algorithm. The base case model developed in Aspen HYSYS® V15 is integrated with MATLAB and the algorithm is applied to carry out rigorous optimization. The optimization results show an increase in the air processing capacity from 500 tons per hour (TPH) to 638.9 TPH with the maximum utilization of the cryogenic energy of LNG. The overall specific energy consumption is increased by 21.66% keeping the same energy consumption of air. Followed by the optimization, the process is then evaluated thermodynamically using the exergy analysis. The analysis demonstrated that the % exergy efficiency of the optimized process is 72.51% with an exergy destruction of 36.42 MW. The overall optimized process may help in providing a more feasible and sustainable design toward the practical implementation of this integrated configuration in context of Pakistan.Item Design & Optimization of BIOMASS GASSIFIER for production of syngas using Computational fluid dynamics(Library Information Services, COMSATS University Islamabad, Lahore Campus, 2020) Noor UL Islam; SP18-RCH-004; Dr. Shehzad Khuram; LHR TP 5954The design of gasification of biomass and coal process is to be enhanced by simulating process parameters and methods with computer software i.e Ansys 14.5 The Properties and characteristics of fluid flow participates for optimization of process. Hence computational fluid dynamics is being used from “Ansys 14.5” Software. Gasification is one of a naturally pleasant solution and is relatively new amongst all the methods available for the manufacture of energy by consuming biomass method. By restricted oxidation, gasification is essential thermo-chemical conversion at higher temperature of carbon-based materials. Any small value carbonaceous compounds similarly biomass, fuel coke, and metropolitan waste and processing plant residues can be recycled for production of great efficiency energy with gasification. As CO2 in air absorbed carbon content of biomass due to this the left CO2 manufacture is zero, so Biomass gasification is principally CO2 neutral. The by-product is identified as syngas (combination of H2, CH4 and CO) taking an elevated fraction of H2 which makes syngas main to all fuels. Above stated causes make gasification of biomass an unexpected substitute for the creation of power and energy. Presently clean and capable source of energy is reflected as the gasification of biomass. Over Practical testing it is time intense and challenging for a FB gasifier by differing the operating settings to obtain optimum conditions. CFD modelling has manifest to be an effective option in current days because from time to time Practical experiments may not be economical and reasonable. Due to nonstop improvement of computational potential, it is capable to carry out such optimization to manage optimum operating settings and design in advance experimental optimization are carried out.Item Green & Sustainable Membranes for Efficient Bioethanol Purification via Pervaporation(Library Information Services COMSATS University Islamabad Lahore Campus, 2023-02-27) Abeera Naeem; SP22-RNE-002; Dr. Muhammad Yasin; LHR TP 8636Traditional membrane technologies, typically reliant on fossil-based polymers and hazardous solvents, pose significant environmental threats. To address these challenges, this study introduces an innovative approach: the development of hydrophobic mixed matrix membranes utilizing waste polyvinyl chloride (PVC) pipes and deep eutectic solvents (DES) based on thymol: urea as green additives. The research focuses on synthesizing two types of membranes: dense and asymmetrical. Each type is evaluated for its efficiency in terms of flux and selectivity. The asymmetric membranes undergo optimization processes, involving adjustments in polymer concentration, co-solvent use, and evaporation time, to enhance pervaporation performance. This optimization aims to achieve maximum ethanol flux and high separation factor. In contrast, the dense recycled PVC membranes exhibit comparable results to conventional polymeric membranes in terms of flux (1.98 kg/m2) and separation factor (16). Significantly, the incorporation of DES into the membrane matrix results in substantial performance improvements. The separation factor enhanced by approximately 125%, alongside a 36% increase in ethanol sorption capacity. Asymmetric membranes particularly demonstrate a higher potential in flux performance, reaching 5.12 kg/m2.hr, in contrast to dense membranes with a flux of 1.98 kg/m2.hr. These findings highlight the effectiveness of using recycled waste materials and DES in membrane fabrication. This approach not only enhances pervaporation performance but also aligns with the goals of green and sustainable membrane technology, offering a promising solution to environmental concerns in the field of membrane separation.Item Catalytic Supercritical Water Gasification of Biomass for Hydrogen Production(Library Information Services, COMSATS University Islamabad, Lahore Campus, 2024) Ali Ahsan; FA22-RNE-003; Dr. Murid Hussain; LHR TP 9306With a focus on rice husk, this study explores the possibilities of supercritical water gasification (SCWG) for the effective synthesis of hydrogen from biomass. Compared to conventional fossil fuels, biomass is a possible substitute, and SCWG provides an energy- and environmentally friendly method of producing hydrogen. The need to maximize catalytic efficiency and reduce this process's environmental impact is what motivates the study. The main focus is on Ni/eggshell catalysts, with the goal of filling up important information gaps about catalytic activity, stability, and the generation of clean hydrogen from biomass sources that are renewable. This research assesses the performance of Ni/eggshell catalysts in biomass SCWG and seeks to establish the suitable working conditions that would yield the highest levels of hydrogen with negligible levels of by-products. The catalyst synthesized with three loadings (5 wt%, 10 wt%, and 20 wt%) in the production of hydrogen in SCW at three different temperatures (370°C, 450°C, and 500°C) and two residence time (60 minutes and 80 minutes) Also, it reviews the Ni/eggshell catalysts in the aspects of activity, stability, and impact on the environment in SCWG. Ni/eggshell proved to be very active in SCWG of rice husk biomass especially with moderate loading of Ni, (10 wt% provided adequate active sites with least chance of particle sintering). According to the experiments, the best conditions for hydrogen production were the temperature 500°C; the residence time of 80 minutes, and the catalyst loading of 10 wt%. These conditions gave the highest gas yields and hydrogen content, and the least solid residues implied that the biomass was almost fully converted. The SEM and XRD studies revealed that there are no morphological changes, and the Ni particles were effectively dispersed and uniformly distributed on the CaO support, thus the catalytic activity was constant. According to the obtained FTIR and XRD results, the catalyst was stable in the course of the reaction.Item Production of Hydrogen Rich Gas Through the Process of Steam Reforming: An Experimental and Simulation Study(Library Information Services, COMSATS University Islamabad, Lahore Campus., 2025-04-01) Muhammad Zain Feroz; CIIT/FA23-RNE-008/LHR; Dr. Um-e-Salma Amjad; LHR TP 9677The objective of this research is to produce Hydrogen, a clean source of energy, through the steam reforming process, from hydrocarbons as feedstock. It emphasizes the development of catalysts that are capable of addressing the challenges of stability and efficiency. This study focuses on the use of tools like DWSIM to determine the operating conditions for enriched hydrogen yield. The research involves catalyst synthesis through the combustion synthesis method to synthesize different catalysts. This method involves using a vaporizer and reactor setup at controlled temperature and pressure. Whereas, after the SR process, the gas composition of the product will be analyzed through the use of a gas analyzer. It will shed light on the efficiency of the process and trace impurities in the product gas. The research focuses on reducing the oxides of carbon in the final product for maximum hydrogen production and to comply with global carbon emission standards.Item Conducting Polymer Coated Carbon Fiber Composites for Enhanced Strain Sensing Applications(Library Information Services, COMSATS University Islamabad, Lahore Campus., 2025-04-01) Fazila Khalil; CIIT/FA23-RNE-011/LHR; Dr. Imran Hassan; LHR TP 9809In modern applications, such as robotics, wearable, and healthcare, strain sensors are crucial as it is possible to accurately measure mechanical defects. The objective of this research was to improve strain sensing of carbon fiber (CF)-based materials by using surface modifications and conducting polymer (CP) coating. Sulfuric acid and nitric acid were used by the ratio of 3 to 1, to etched carbon fiber (e-CF) by making the surface rougher and having more functional groups to improve adhesion to the polymer. Composites consisted of CF coated with polyaniline (PANI) were synthesized through in-situ polymerization and then coated with Poly(3,4-Ethylenedioxythiophene): Polystyrene Sulfonate (PEDOT:PSS) to give composites based on conducting polymers. The structural, chemical and thermal characterization of the synthesized composites was done using X ray diffraction, Fourier-transform infrared spectroscopy, and thermogravimetric analysis. Electrical conductivity and strain-sensing capability were assessed during several forms of bending, including finger, wrist, and elbow motions. The sample with PEDOT:PSS coated on top of PANI coated e-CF showed the highest sensitivity, as well as superior thermal stability and electrical conductivity, compared to the other composites. This study demonstrates that changing the surface and coating with two different types of CP can significantly enhance the overall characteristics and performance of CF-based composites. These findings indicate a potential interest in employing CP coated CF composites as high performance strain sensors in healthcare, wearable electronics, robotics, and smart textiles as well.Item Development of Functional Materials for Energy Harvesting Devices(Library Information Services, COMSATS University Islamabad, Lahore Campus., 2025-04-01) Mubashra Mushatq; CIIT/FA23-RNE-010/LHR; Dr. Maria Mustafa; LHR TP 9679The need for new materials with enhanced functionality, structural stability, and energy conversion efficiency has increased due to the growing need for renewable energy solutions. Functional energy materials because of their large surface area, adjustable porosity, find their versatility in various applications, such as sensors, energy storage, and energy harvesting devices. The thesis work will explore and optimize the importance of the development of advanced functional material on energy harvesting devices, i.e., triboelectric nanogenerator (TENGs) to address the increasing demands of efficient and sustainable renewable energy sources. The research lies in the synthesis of Zeolitic Imidazolate Framework-67 (ZIF-67), Polyvinylidene Fluoride (PVDF), and Sodium Niobate (NaNbO3) materials owing to their large surface area, controllable porosity, and sturdiness to facilitate energy conversion performance. Such materials were reduced to form thin films by careful manufacturing methods, e.g. electrohydrodynamic (EHD) spray deposition, drop casting, etc. and inserted within TENG devices with aluminum and copper electrodes to maximize charge transfer and surface functionality. To explore the materials structural, optical, and electrical properties, UV-Vis spectroscopy, FTIR, SEM, and I-V measurements were performed in order to achieve thorough characterization of the materials as they would be used in energy applications. Tests determined that performance of TENGs with these functional materials were much greater than those of a baseline as the NaNbO3 -PVDF system showed an outstanding power generation owing to its piezoelectric and ferroelectric characteristics. Nevertheless, compatibility issues of the material were found at ZIF-67/NaNbO3 composite, which supports the idea of making a strategic selection of material. These results suggest the opportunities of custom functional materials to instruct energy harvesting technologies, which can provide scalable and sustainable energy supply of flexible electronics, sensing and energy storage.